Sodium thioether macrocyclic chemistry: remarkable homoleptic octathia coordination to Na(+).
نویسندگان
چکیده
Unprecedented homoleptic octathioether macrocyclic coordination to Na(+) in [Na([24]aneS8)](+) has been achieved by using Na[B{3,5-(CF3)2-C6H3}4] as a source of "naked" Na(+) ions and confirmed crystallographically, with d(Na-S) = 2.9561(15)-3.0524(15) Å. Density functional theory calculations show that there is electron transfer from the S 3p and C 2p valence orbitals of the ligand to the 3s and 3p orbitals of the Na(+) ion upon complexation.
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 54 6 شماره
صفحات -
تاریخ انتشار 2015